Vegetable Oil Fuel Experiments
Vegetable Oil Fuel
Waste vegetable oil which has been filtered.
Many vegetable oils have similar fuel properties to diesel fuel,
except for higher viscosity and lower oxidative stability. If these
differences can be overcome, vegetable oil may substitute for #2 Diesel
fuel, most significantly as engine fuel or home heating oil.
For engines designed to burn #2 diesel fuel, the viscosity of vegetable oil must be lowered to allow for proper atomization
of fuel, otherwise incomplete combustion and carbon build up will
ultimately damage the engine. Many enthusiasts refer to vegetable oil
used as fuel as waste vegetable oil (WVO) if it is oil that was discarded from a restaurant or straight vegetable oil (SVO) or pure plant oil (PPO) to distinguish it from biodiesel.
History
The first known use of vegetable oil as fuel in a diesel engine was a demonstration of an engine built by the Otto company and designed to burn mineral oil, which was run on pure peanut oil at the 1900 World's Fair. Late in his career, Rudolf Diesel investigated using vegetable oil to fuel engines of his design, and in a 1912 presentation to the British Institute of Mechanical Engineers,
he cited a number of efforts in this area and remarked, "The fact that
fat oils from vegetable sources can be used may seem insignificant
today, but such oils may perhaps become in course of time of the same
importance as some natural mineral oils and the tar products are now."[1]
Periodic petroleum shortages spurred research into vegetable oil as
a diesel substitute during the 30s and 40s, and again in the 70s and
early 80s when straight vegetable oil enjoyed its highest level of
scientific interest. The 1970s also saw the formation of the first
commercial enterprise to allow consumers to run straight vegetable oil in their automobiles, Elsbett of Germany. In the 1990s Bougainville conflict, islanders cut off from oil supplies due to a blockade used coconut oil to fuel their vehicles.[2]
Academic research into straight vegetable oil fell off sharply in the 80s with falling petroleum prices and greater interest in biodiesel as an option that did not require extensive vehicle modifications.
Application and usability
Older diesel Mercedes are popular for conversions to biodiesel or waste vegetable oil.
While engineers and enthusiasts have been experimenting with using
vegetable oils as fuel for a diesel engine since at least 1900, it is
only recently that the necessary fuel properties and engine parameters
for reliable operation have become apparent. A number of peer reviewed
studies exists that show reliable long term use of vegetable oil; the
German Deutz F3l912W.[3] and a high speed common rail engine fitted to a Mercedes-Benz 220 C Class[4]
Most diesel car engines are suitable for the use of SVO, also commonly called Pure Plant Oil
(PPO), with suitable modifications. Principally, the viscosity and
surface tension of the SVO/PPO must be reduced by preheating it,
typically by using waste heat from the engine or electricity, otherwise
poor atomization, incomplete combustion and carbonization may result. One common solution is to add a heat exchanger, and an additional fuel tank for "normal" diesel fuel (petrodiesel or biodiesel)
and a three way valve to switch between this additional tank and the
main tank of SVO/PPO. (This aftermarket modification typically costs
about $1200 USD.)[5]
The engine is started on diesel, switched over to vegetable oil as soon
as it is warmed up and switched back to diesel shortly before being
switched off to ensure that no vegetable oil remains in the engine or
fuel lines when it is started from cold again. In colder climates it is
often necessary to heat the vegetable oil fuel lines and tank as it can
become very viscous and even solidify.
Single tank conversions have been developed, largely in Germany,
which have been used throughout Europe. These conversions are designed
to provide reliable operation with rapeseed oil that meets the German
rapeseed oil fuel standard DIN
51605. Modifications to the engines cold start regime assist combustion
on start up and during the engine warm up phase. Suitably modified indirect injection (IDI) engines have proven to be operable with 100% PPO down to temperatures of -10°C. Direct injection (DI) engines generally have to be preheated with a block heater or diesel fired heater. The exception is the VW Tdi (Turbocharged Direct Injection)
engine for which a number of German companies offer single tank
conversions. For long term durability it has been found necessary to
reduce the oil change frequency and to pay increased attention to
engine maintenance.
With unmodified engines the unfavorable effects may be reduced by
blending, or "cutting", the SVO/PPO with diesel fuel; however, opinions
vary as to the efficacy of this. Some WVO mechanics have found higher rates of wear and failure in fuel pumps and piston rings.
This can generally be attributed to the use of oils with properties or
contaminants that make them unsuitable for use in this type of
application, poorly maintained engines, unsuitable engine modifications
or operating regimes.
Many cars powered by indirect injection engines supplied by in-line injection pumps, or mechanical Bosch injection pumps are capable of running on pure SVO/PPO in all but winter temperatures. Indirect injection Mercedes-Benz vehicles with in-line injection pumps and cars featuring the PSA XUD engine tend to perform reasonably, especially as the latter is normally equipped with a coolant heated fuel filter.
Engine reliability would depend on the condition of the engine.
Attention to maintenance of the engine, particularly of the fuel
injectors, cooling system and glow plugs will help to provide
longevity. Ideally the engine would be converted.
Properties
The main form of SVO/PPO used in the UK is rapeseed oil (also known
as canola oil, primarily in the United States and Canada) which has a
freezing point of -10°C. However the use of sunflower oil, which
freezes at -17°C, is currently being investigated as a means of
improving cold weather starting. Unfortunately oils with lower gelling
points tend to be less saturated (leading to a higher iodine number) and polymerize more easily in the presence of atmospheric oxygen.
Examples
Some Pacific island nations are using coconut oil
as fuel to reduce their expenses and their dependence on imported fuels
while helping stabilize the coconut oil market. Coconut oil is only
usable where temperatures do not drop below 17 degrees Celsius (62
degrees Fahrenheit), unless two-tank SVO/PPO kits or other tank-heating
accessories, etc. are used. Fortunately, the same techniques developed
to use, for example, canola and other oils in cold climates can be
implemented to make coconut oil usable in temperatures lower than 17
degrees Celsius.
Home heating
With often minimal modification, most residential furnaces and
boilers which are designed to burn No. 2 heating oil can be made to
burn either biodiesel or filtered, preheated waste vegetable oil. These
are generally not as clean-burning as petroleum fuel oil, but if
processed at home, by the consumer, can result in considerable savings.
Many restaurants will give away their used cooking oil either free or
at minimal cost, and processing to biodiesel is fairly simple and
inexpensive. Burning filtered WVO directly is somewhat more
problematic, since it is much more viscous, but it can be accomplished
with suitable preheating. WVO can thus be a very economical heating
option for those with the necessary mechanical and experimental
aptitude.
Combined Heat and Power
A number of companies offer compressed ignition engine generators optimized to run on plant oils where the waste engine heat is recovered for heating.
Availability
Waste vegetable oil
As of 2000, the United States was producing in excess of 11 billion liters of waste vegetable oil annually, mainly from industrial deep fryers in potato processing plants, snack food factories and fast food restaurants.
If all those 11 billion liters could be collected and used to replace
the energetically equivalent amount of petroleum (an ideal case),
almost 1% of US oil consumption could be offset.[6] However, use of waste vegetable oil as a fuel competes with some already established uses.
Pure vegetable oil (pure plant oil)
Pure plant oil (PPO) (or Straight Vegetable Oil (SVO)), in contrast
to waste vegetable oil, is not a byproduct of other industries, and
thus its prospects for use as fuel are not limited by the capacities of
other industries. Production of vegetable oils for use as fuels is
theoretically limited only by the agricultural capacity of a given
economy.
Oils used for biofuel
A number of the oils listed above are used for biofuel (biodiesel and Straight Vegetable Oil) in addition to having other uses. A number of oils are used only as biofuel.[77][78]
Although diesel engines were invented, in part, with vegetable oil in mind,[79] diesel fuel is almost exclusively petroleum-based. Rising oil prices have made biodiesel more attractive. Vegetable oils are evaluated for use as a biofuel based on:
- Suitability as a fuel, based on flash point, energy content, viscosity, combustion products and other factors
- Cost, based in part on yield, effort required to grow and harvest, and post-harvest processing cost
Multipurpose oils also used as biofuel
The oils listed immediately below are all (primarily) used for other purposes - all but tung oil are edible - but have been considered for use as biofuel.
- Castor oil, lower cost than many candidates. Kinematic viscosity may be an issue.[80]
- Coconut oil (copra oil), promising for local use in places that produce coconuts.[81]
- Corn oil, appealing because of the abundance of maize as a crop.
- Cottonseed oil, shown in one study not to be cost effective when compared with standard diesel.[82]
- False flax oil, from Camelina sativa, used in Europe in oil lamps until the 18th century.[49]
- Hemp oil, relatively low in emissions. High flash point. Production is problematic in some countries because of its association with marijuana.[83]
- Mustard oil, shown to be comparable to Canola oil as a biofuel.[84]
- Palm oil, very popular for biofuel, but the environmental impact from growing large quantities of oil palms has recently called the use of palm oil into question.[85]
- Peanut oil, used in one of the first demonstrations of the Diesel engine in 1900.[79]
- Radish oil. Wild radish contains up to 48% oil, making it appealing as a fuel.[86]
- Rapeseed oil, the most common base oil used in Europe in biodiesel production.[78]
- Ramtil oil, used for lighting in India.[87]
- Rice bran oil, appealing because of lower cost than many other vegetable oils. Widely grown in Asia.[88]
- Safflower oil, explored recently as a biofuel in Montana.[89]
- Soybean oil, not economical as a fuel crop, but appealing as a byproduct of soybean crops for other uses.[78]
- Sunflower oil, suitable as a fuel, but not necessarily cost effective.[90]
Inedible oils used only or primarily as biofuel
These oils are extracted from plants that are cultivated solely for producing oil-based biofuel.[93] These, plus the major oils described above, have received much more attention as fuel oils than other plant oils.
- Algae oil, recently developed by MIT scientist Isaac Berzin. Byproduct of a smokestack emission reduction system.[94][95]
- Copaiba, an oleoresin tapped from species of genus Copaifera. Used in Brazil as a cosmetic product and a major source of biodiesel.[96]
- Honge oil, pioneered as a biofuel by Udipi Shrinivasa in Bangalore, India.[97]
- Jatropha oil, widely used in India as a fuel oil. Has attracted strong proponents for use as a biofuel.[98][99]
- Jojoba oil, from the Simmondsia chinensis, a desert shrub.[100]
- Milk bush, popularized by chemist Melvin Calvin in the 1950s. Researched in the 1980s by Petrobras, the Brazilian national petroleum company.[101]
- Petroleum nut oil, from the Petroleum nut (Pittosporum resiniferum ) native to the Philippines. The Philippine government once explored the use of the petroleum nut as a biofuel.[102]
Legal implications
The conversion of an automobile engine to burn vegetable oil is not legal under US Environmental Protection Agency guidelines.[7] The EPA
has not fined anyone for doing so, but certain laws may have to change
— or a certification process may need to be established — before VO
conversions become more popular in the US.
Taxation of fuel
Taxation on SVO/PPO as a road fuel varies from country to country,
and it is possible the revenue departments in many countries are even
unaware of its use, or feel it insufficiently significant to legislate.
Germany offers 0% taxation, resulting in their leading on most
developments of the fuel use. However SVO/PPO as a road fuel will be
taxed with 0,09 €/liter on January, the 1st of 2008 in Germany. From
thereon it will rise up to 0,45 €/liter until 2012.
There seems to be no clear taxation system in the USA, however given
the low rate of fuel taxation, it is unlikely to face anything
unfavorable, although charges could vary from state to state.
Production of biodiesel in some US regions may require motor fuel taxes
to be paid, which are typically used to fund road construction costs.[8]
The Government of Canada exempted biodiesel from the federal excise tax on diesel in the March 2003 budget. In Ireland
a pilot scheme is currently running (as of April 2006) whereby eight
suppliers have been approved to sell SVO/PPO for use as a fuel without
the payment of excise duty (Value Added Tax at 21% still applies, SVO from any other source still attracts excise duty at 36.8058 Euro cents per litre plus 21% VAT). Despite its use being common in France, it would appear there has been no legislation to cover this.
In the UK, it is legal once duty on the fuel is paid.[9] In the UK, drivers using SVO/PPO have been prosecuted for failure to pay duty to Her Majesty's Revenue and Customs.
The rate of taxation on SVO was originally set at a reduced rate of
27.1p per litre, but in late 2005, HMRC started to enforce the full
diesel excise rate of 47.1p per litre.
Following a review late 2006,[10] HM Revenue & Customs
has announced changes regarding the administration and collection of
excise duty of biofuels and other fuel substitutes (Veg Oil). The
changes came into effect on June 30, 2007.
There is no longer a requirement to register (enter premises) or pay
duty on vegetable oil used as road fuel if you 'produce' (use) less
than 2500 litres per year.[11] For those producing over this threshold the biodiesel rate now applies.
HMRC argued that SVOs/PPOs on the market from small producers did
not meet the official definition of "biodiesel" in Section 2AA of The
Hydrocarbon Oil Duties Act 1979 (HODA), and consequently was merely a
"fuel substitute" chargeable at the normal diesel rate. Such a policy
seemed to contradict the UK Government's commitments to the Kyoto Protocol
and to many EU directives and had many consequences, including an
attempt to make the increase retroactive, with one organization being
presented with a £16,000 back tax bill. This change in the rate of
excise duty has effectively removed any commercial incentive to use
SVO/PPO, regardless of its desirability on environmental grounds;
unless waste vegetable oil can be obtained free of charge, the combined
price of SVO/PPO and taxation for its use usually exceeds the price of
mineral diesel. HMRC's interpretation is being widely challenged by the
SVO/PPO industry and the UK pure Plant Oil Association (UKPPOA) has been formed to represent the interests of people using vegetable oil as fuel and to lobby parliament.[12]
References
- ^ Knothe, Gerhard (2001). "Historical Perspectives on Vegetable Oil-Based Diesel Fuels". Inform 12 (11): 1103-1107.
- ^ The Coconut Revolution at the Internet Movie Database (2000) a documentary film
- ^ Hawkins, C.S.;
Fuls, J.; and F.J.C. Hugo. "Engine Durability Tests with Sunflower Oil
in an Indirect Injection Diesel Engine." SAE Paper 831357.
- ^ Bialkowski, M.T.; Pekdemir, T.; Reuben, R.; Brautsch, M.; Towers, D. P.; Elsbett, G. (2005). "Preliminary Approach Towards a CDI System Modification Operating on Neat Rapeseed Oil" (PDF). Journal of KONES 12. ISSN 4005 12341 4005. Retrieved on 2007-10-24.
- ^ Henderson, Bruce. "Driver ticketed for using biofuel: Vegetable oil sticks him with $1,000 fine", The Charlotte Observer, June 11, 2007. Retrieved on 2007-06-24.
- ^ See Greenhouse gas emissions by the United States
- ^ Davis, Erica. "Gas-Price Spike Boosts Alternative-Fuel Convert", Wall Street Journal Online. Retrieved on 2007-08-30.
- ^ Henderson, Bruce. "Driver ticketed for using biofuel: Vegetable oil sticks him with $1,000 fine", The Charlotte Observer, June 11, 2007. Retrieved on 2007-06-24.
- ^ UK Hydrocarbon Oil duty rates. HM Revenue & Customs. Retrieved on 2007-06-24.
- ^ HM Revenue & Customs (December 2006). Review of the definition of Biodiesel in Hydrocarbon Oil Duties Act 1979: Summary of Responses and Findings (pdf). Retrieved on 2007-05-04.
- ^ Revenue & Customs Brief 43/07. HM Revenue & Customs. Retrieved on 2007-06-24.
- ^ Fuel-Duty and VAT on Pure Vegetable Oil. Biomotors.co.uk. Retrieved on 2007-05-04.
External links
Vegetable Oil Fuel Economy
Vegetable oil economy is the potential of vegetable oil to replace fossil fuels in the economy and how it compares to other potential replacements. Vegetable oils are the basis of biodiesel, which can be used like conventional diesel. Some vegetable oil blends are used in unmodified vehicles, but straight vegetable oil needs specially prepared vehicles which have a method of heating the oil to reduce its viscosity and surface tension. Vegetable oil can also be used as feedstock for an oil refinery. The list of vegetable oils is long, the vegetable oil market is growing. The availability of biodiesel around the world is increasing. There is significant research in algaculture methods with the intent to make biofuel from algae.
Attribution: Soybean Board of Nebraska [1]
Future of energy for world economy
There is a limited amount of fossil fuel inside the Earth. Since the current world energy resources and consumption is mainly fossil fuels, we are very dependent on them for both transportation and electric power generation. The Hubbert peak theory predicts that oil depletion
will result in oil production dropping off in the not too distant
future. As time goes on our economy will have to transition to some alternative fuels. Fossil fuels have solved two problems which could be separately solved in the future: the problem of a source of primary energy and of energy storage. Along with straight vegetable oil and biodiesel, some energy technologies that could play an important part in the future include :
Environmentally friendly fuel
Plants use sunlight and photosynthesis to take CO2 out of the Earth's atmosphere to make vegetable oil. The same CO2 is then put back after it is burned in an engine. Thus vegetable oil does not increase the CO2 in the atmosphere, and does not contribute to the problem of greenhouse gas. It is really a way of catching and storing solar energy. It is a true renewable energy.
Burning fossil fuels releases sulfur dioxide and other harmful air pollution.[2]
Because vegetable oil has not been inside the earth for millions of
years, it is not contaminated with things like sulfur and burns much
cleaner, even than ultra low sulphur diesel. Burning fossil fuels also contributes to the greenhouse gas problem.
Note that if fossil fuels are used in any aspect of production and
distribution (making fertilizer, tractors, fuel trucks, etc.), then
there would be some contribution to pollution. For it to be 100%
non-polluting all aspects of vegetable oil production would have to be
non-polluting as well.
Safety
Vegetable oil is essentially non-toxic relative to other fuels such as gasoline, petroleum-based diesel, ethanol, or methanol, and has a much higher flash point (approximately 275-290 °C)[3]. The higher flash point reduces the risk of accidental ignition. Some types of vegetable oil are edible.
Generation and storage
Technologies of hydrogen economy, batteries, compressed air energy storage, and flywheel energy storage address the energy storage problem but not the source of primary energy. Other technologies like fission power, fusion power, and solar power address the problem of a source of primary energy but not energy storage. Vegetable oil addresses both the source of primary energy and of energy storage.
The cost and weight to store a given amount of energy as vegetable oil
is relatively low compared to many of the potential replacements for fossil fuels.
Transportation
For transportation the energy density
and cost to store the energy are important. If the density is low or
the cost is too high it is not practical to make vehicles with
reasonable range. Vegetable oil and biodiesel are close to regular
diesel.
Another potential issue for new fuels is the Catch-22
conundrum: if there needs to be expensive new infrastructure before
people will make cars running on a new fuel, and there need to be new
cars before people will build the infrastructure, how can the
transition ever be made? With vegetable oil this is not nearly the
problem that it is with some other fuels. The transition from petroleum
oil based transportation to vegetable oil based transportation could be
gradual and relatively easy compared to hydrogen, ethanol, and most
other alternatives. Vegetable oil is used for transportation in four
different ways:
- Vegetable oil blends
- Mixing vegetable oil with diesel lets ussers get some of the
advantages of burning vegetable oil and is often done with no
modification to the vehicle. [4]
- Biodiesel - If vegetable oil is transesterified it becomes biodiesel.
Biodiesel burns like normal diesel and works fine in any diesel engine.
The name just indicates that the fuel came from vegetable oil.
- Straight vegetable oil - Straight vegetable oil works in diesel engines if it is heated first. [5]
Some diesel engines already heat their fuel, others need a small
electric heater on the fuel line. How well it works depends on the
heating system, the engine, the type of vegetable oil (thinner is
easier), and the climate (warmer is easier). Some data is available on
results users are seeing. [6] As vegetable oil has gotten more popular as a fuel, engines are being designed to handle it better. The Elsbett engine is designed to run on straight vegetable oil. [7]
However, as of the start of 2007, it seems that there are not any
production vehicles warrantied for burning straight vegetable oil,
although Deutz offer a tractor and John Deere are known to be in late stages of engine development. There is a German rapeseed oil fuel standard DIN
51605. At this point straight vegetable oil is only a niche market
although the market segment in Germany is rapidly growing with large
haulage vehicle fleets adopting the fuel, largely for economic reasons.
A growing number of decentralised oil mills provide a large part of
this fuel. [8]
- Vegetable oil refining - Vegetable oil can be used as feedstock for an oil refinery. There it can be transformed into fuel by hydrocracking (which breaks big molecules into smaller ones using hydrogen) or hydrogenation (which adds hydrogen to molecules). These methods can produce gasoline, diesel, or propane. Some commercial examples of vegetable oil refining are NExBTL, H-Bio, and the ConocoPhilips process. [9]
The transition can start with biodiesel, vegetable oil refining, and vegetable oil blends,
since these technologies do not require the capital outlay of
converting an engine to run on vegetable oils. Because it costs to
convert vegetable oil into biodiesel it is expected that vegetable oil
will always be cheaper than biodiesel. After there are production cars
that can use straight vegetable oil
and a standard type available at gas stations, consumers will probably
choose straight vegetable oil to save money. So the transition to
vegetable oil can happen gradually.
Electricity generation
Vegetable oil is a convenient safe way to store energy for transportation and is similar to the way things have been done. For electricity generation these things are not so important. The most important thing is cost for the electricity produced. The world coal
reserves are far larger than the world oil reserves. So replacing the
coal used in power plants is not as urgent as replacing the oil used
for transportation. The motivation to use vegetable oil for power
generation is much less than for transportation. Other methods, like nuclear power, fusion power, wind power and solar power, may provide cheaper electricity, so vegetable oil may only be used in peaking power plants and small power plants, as diesel is limited to today. There is at least one 5 MW power plant that runs on biodiesel. [10]. MAN B&W Diesel, Wartsila and other companies produce engines suitable for power generation that can be fueled with pure plant oils.
Market / cost / price / taxes
In some countries, filling stations sell bio-diesel more cheaply than conventional diesel.
Availability of biodiesel around the World
is improving. It is estimated that by 2010 the market for biodiesel
will be 7.5 billion litres (2 billion USgallons) in the U.S and 9.5
billion litres (2.5 billion USgallons) in Europe. [11] Biodiesel currently has 3% of the diesel market in Germany and is the number 1 alternative fuel.[12]
The German government has a Biofuels Roadmap in which they expect to
reach 10% biofuels by 2010 with the diesel 10% coming from fuel made
from vegetable oil. [13]
From 2005 to 2007 a number of types of vegetable oil have doubled in
price. The rise in vegetable oil prices is largely attributed to
biofuel demand. [14]
Much of the fuel price at the pump is due to fuel tax.
If you buy vegetable oil at the grocery store it does not have such
high taxes. So at times people have bought vegetable oil at the store
for their cars because it was cheaper. They did this in spite of the
fact that packaging by the gallon adds to the cost and it was illegal
to use in a car since no fuel tax had been paid on it. [15]
Since vegetable oil (even as biodiesel) does not contribute to greenhouse gas, governments may tax it much less than gasoline as they have done with ethanol. [16] This would help them reach Kyoto protocol targets.
Production in sufficient quantity
The World production of vegetable oil in 2004/5 was 387.7 million tonnes. Much of this is from Oil Palm, and palm oil production is growing at 5% per year. [17]
At about 7.5 lb/USgal (900 g/L) this is about 110 billion USgallons
(430 billion L). Currently vegetable oil is mostly used in food and
some industrial uses with a small percentage used as fuel.
In 2004 the US consumed 530 billion litres (140 billion USgal) of gasoline and 150 billion litres (40 billion USgal) of diesel. [18] In biodiesel it says oil palm produces 5940 litres per hectare (635 USgal/acre) of palm oil
each year. To make 180 billion US gallons of vegetable oil each year
would require 1,150,000 square kilometres (443,000 sq mi) or a square
of land 1070 kilometres (666 miles) on a side.
"The gradual move from oil has begun. Over the next 15 to 20 years we
may see biofuels providing a full 25 percent of the world's energy
needs. While the move is good for reducing greenhouse emissions,
soaring oil prices have encouraged most countries to 'go green' by
switching to greater use of biofuels." - Alexander Müller, Assistant
Director-General of Sustainable Development at the FAO. [19]
Algaculture could potentially produce far more oil per unit area. [20] Results from pilot algaculture projects using sterile CO2 from powerplant smokestacks look promising.
Genetic modifications to soybeans
are already being used. Genetic modifications and breeding can increase
vegetable oil yields. From 1979 to 2005 the soybean yield in bushels
per acre more than doubled. [21] A company has developed a variety of camelina sativa that yields 20% more oil than the standard variety. [22]
Environmental effects
Jungle burned for agriculture in southern Mexico.
There is concern that the current growing demand for vegetable oil is causing deforestation, with old forests being replaced with Oil Palms. [23]
When land is cleared it is often burned, which releases lots of CO2.
Vegetable oil production would have to increase substantially to
replace gasoline and diesel. With current technology such an increase
in production would have a substantial environmental impact. [24]
While not immediately toxic to wildlife, spills are still
potentially dangerous due to the physical damage caused to ecosystems.
These effects may include contamination of tissues impeding their vital
functions (e.g. plant stomata, fish gills, bird feathers, and mammal hair), increased biological oxygen demand and chemical oxygen demand leading to deoxygenation of water, and infiltration into soil sediments and aquifer contamination.
Food vs fuel debate
In some poor countries the rising price of vegetable oil is causing problems. [25] [26]
There are those that say using a food crop for fuel sets up competition
between food in poor countries and fuel in rich countries. Some propose
that fuel only be made from non-edible vegetable oils like jatropha oil.
Others argue that the problem is more fundamental. Farmers can switch
from producing food crops to producing biofuel crops to make more
money, even if the new crops are not edible. [27] [28] The law of supply and demand
predicts that if less farmers are producing food the price of food will
rise. It may take some time, as farmers can take some time to change
which things they are growing, but increasing demand for biofuels is
likely to result in price increases for many kinds of food. Some have
pointed out that there are poor farmers and poor countries making more
money because of the higher price of vegetable oil. [29]
Urgency of transition to renewable transportation
- Optimist's view: As oil gets more expensive, people will invest in
technologies to increase the supply of oil from petroleum and renewable
sources. If renewable sources are less expensive than petroleum, or if
the environmental effects are preferred, then they will eventually
replace petroleum. As the price of oil goes up, more people will be
willing to drive efficient vehicles, like hybrids or diesels, even if
capital costs remain higher. [30] The transition will have a diffusion of innovation
time on the order of 20 to 50 years. This should be enough time to
figure out how to make lots of vegetable oil, assuming resources are
put toward research and development. To the extent that a viable source
of oil is not found, then electric vehicles will be produced in greater numbers to supplement the oil-based transportation sector, and reduce demand for oil. [31]
- Pessimist's view: The effects of even a small drop in production can be devastating. For instance, during the 1973 oil crisis, world production of oil dropping 5% caused the price of oil to nearly quadruple. [32]
If forest land needed to be reclaimed to grow energy crops, then the
extent of deforestation could be environmentally disastrous. We need to
change our ways so we don't need so much fuel. [33] For example, plug-in hybrid electric vehicles and diesel hybrids
use much less fuel. Alternative technologies need to be invested in and
brought to market so that they will be available if and when they are
needed. To delay is to invite disaster.
Algae for vegetable oil production
-
The silver bullet for the vegetable oil economy is harvesting vegetable oil from algae.
Some species of algae contain as much as 50% vegetable oil. Algae have
very high growth rates compared to plants normally used to produce
vegetable oil. Potentially algae could produce much more oil per area
of land than current farming methods. [34]
So producing vegetable oil this way should result in less deforestation
and less competition for food production land. One expert wrote: "As
demonstrated here, microalgal biodiesel is technically feasible. It is
the only renewable biodiesel that can potentially completely displace
liquid fuels derived from petroleum. Economics of producing microalgal
biodiesel need to improve substantially to make it competitive with
petrodiesel, but the level of improvement necessary appears to be
attainable. " [35]
Where there is existing electricity generation using fossil fuels, there is a source of sterile CO2. This makes algaculture
much easier. To grow algae you need lots of CO2, but if you get it from
air you will also get all kinds of other organisms, some of which eat
algae. Getting CO2 from a smokestack works out really well. Governments
trying to address the external costs of coal power plants may have a carbon tax or carbon credit that provides additional motivation to use CO2 from smokestacks. Several commercial pilot plants are under construction. [36]
If all CO2 emitting powerplants had algaculture farms attached to them that were making biofuel from algae, the total vegetable oil produced would be about equal to world transportation needs. One could run a powerplant off the vegetable oil produced by it, in which case the electricity production would be carbon neutral.
However, because coal is so abundant and transportation fuel so
valuable, the common case would probably be coal coming into the
powerplant and carbon going out as vegetable oil to be used in
transportation. After the carbon is used the second time for
transportation, it would be released into the atmosphere as CO2. So the
combination of powerplant and transportation would then release as much
CO2 as either does alone now. The other benefit is that transportation
fuel would last as long as coal, which is expected to be a long time.
There is substantial research and development work in this area but
as of 2007 there is no commercial vegetable oil produced from algae and
used as biofuel. If and when the commercialization challenges are
overcome, vegetable oil production could expand very rapidly.
Net energy gain
To evaluate potential sources of primary energy it is useful to look at the net energy gain or EROEI. This is the ratio of energy out to energy input. These numbers can change as the technology changes. For example, early photovoltaics technology had EROEI numbers of less than 1 but current cells achieve net energy gain numbers of 10 to 30.
References
- ^ http://nesoybeans.unl.edu/
- ^ The Hidden Cost of Fossil Fuels
- ^ Chemical1-6_1
- ^ Vegetable Oil as Vehicle Fuel
- ^ Straight vegetable oil as diesel fuel: Journey to Forever
- ^ Using Vegetable oil as a diesel fuel - database
- ^ http://www.elsbett.com/engl/index.htm
- ^ Stotz, Kathrin; Remmele, Edgar (200). "Oil Processing in Decentralised Oil Mills - Results of a Survey" (PDF). Landtechnik 60 (1): 16–1. Retrieved on 2007-10-25.
- ^ Green Car Congress: ConocoPhillips Begins Production of Renewable Diesel Fuel at Whitegate Refinery
- ^ Texas power plant runs on biodiesel | CNET News.com
- ^ Biodiesel to drive up the price of cooking oil | CNET News.com
- ^ ADM Biodiesel: Hamburg, Leer, Mainz
- ^ Biofuels News (Green Portal)
- ^ Farmers Journal: Vegetable oil prices soar - 17 November 2007
- ^ Run A Diesel Car On Vegetable Oil
- ^ WashingtonWatch.com - H.R. 196, The Renewable Fuels and Energy Independence Promotion Act of 2007
- ^ Food Outlook - No. 4 December 2005
- ^ Biofuels for Transportation
- ^ IRIN
Africa | East Africa Southern Africa West Africa | Malawi Mozambique
Senegal Tanzania South Africa | AFRICA: Food to eat or to run your
car ? | Economy Environment Food Security | News Item
- ^ http://www1.eere.energy.gov/biomass/pdfs/biodiesel_from_algae.pdf
- ^ ERS/USDA Briefing Room - Soybeans and Oilcrops: Market Outlook
- ^ Biotech | Seeding the way to better biofuels | Seattle Times Newspaper
- ^ Why is oil palm replacing tropical rainforests
- ^ biofuelwatch: home
- ^ http://www.abc.net.au/news/stories/2007/07/19/1982450.htm
- ^ The other oil shock: Vegetable oil prices soar - International Herald Tribune
- ^ Food versus fuel debate escalates
- ^ How Food and Fuel Compete for Land by Lester Brown - The Globalist > > Global Energy
- ^ The Economist – The End Of Cheap Food.
- ^ Hybrid Universe Expanding Rapidly
- ^ Marshall Brain's Blog: Peak oil will be a non-event
- ^ Peak Oil: Life After the Oil Crash
- ^ Why is oil palm replacing tropical rainforests
- ^ http://www1.eere.energy.gov/biomass/pdfs/biodiesel_from_algae.pdf
- ^ Chisti, Yusuf (2007). "Biodiesel from microalgae". Biotechnology Advances (25): 294-306.
- ^ McKenna, Phil (7 October 2006). "From smokestack to gas tank". New Scientist 192 (2572): 28-29. Reed Business Information. ISSN: 1032 1233.
- ^ R-Squared Energy Blog: Grain-Derived Ethanol: The Emperor’s New Clothes
- ^ John Sheehan, Vince Camobreco, James Duffield, Michael Graboski, Housein shapouri (May 1998). "Life Cycle Inventory of Biodiesel and Petroleum Diesel for Use in an Urban Bus"
(PDF (1.9 Mb)). Final Report. United States Department of Agriculture
jointly with United States Department of Energy. Retrieved on 2007-01-02.
^ Ethanol and, to a lesser degree, methanol are the other major types of biofuel.
^ a b c Castoroil.in: Bio fuels. Retrieved on 2006-07-25.
^ a b Biodiesel America: Dr. Diesel's Invention. Retrieved on 2006-07-31.
^ CastorOil.in: Castor Oil as Biodiesel & Biofuel. Retrieved on 2007-07-25.
^ Coconut Oil as a Biofuel in Pacific Islands - Challenges & Opportunities (PDF). South Pacific Applied Geoscience Web site.
^ Ronald C. Griffin and Madhu Jamallamudi. The Economic Circumstances of Cottonseed Oil as Biodiesel (PDF).
^ Hemp car: Pollution: Petrol vs Hemp. Retrieved on 2006-07-26.
^ Office of University Research and Education (November 2001). Biodiesel from Yellow Mustard Oil. U.S. Department of Transportation.
^ Wes Jackson (Fall 1999). "Clearcutting the Last Wilderness". The Land Report (65). The Land Institute.
^ Australian Agronomy Society: Bio-diesel, farming for the future. Retrieved on 2006-02-26.
^ B.L. Axtell from research by R.M. Fairman (1992). "Noog abyssinia", Minor oil crops. FAO. Retrieved on 2006-11-17.
^ Orchidea Rachmaniah, Yi-Hsu Ju, Shaik Ramjan Vali, Ismojowati Tjondronegoro, and Musfil A.S. (2004). "A Study on Acid-Catalyzed Transesterification of Crude Rice Bran Oil for Biodiesel Production" (PDF). World Energy Congress (19).
^ Jesus Fernandez. Safflower oil in your tank. Queen City News.
^ European Energy Crops InterNetwork: Sunflower crop feasibility for biodiesel production in Spain. Retrieved on 2006-07-26.
^ Journey to Forever: Bio-diesel Yield. Retrieved on 2006-07-26.
^ The Chemistry of Biodiesel. Retrieved on 2006-07-26.
Weblinks
This article is licensed under the GNU Free Documentation License. It uses material from Wikipedia Encyclopedia article "Straight Vegetable Oil"
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